Efficient passivated phthalocyanine-quantum dot solar cells.
نویسندگان
چکیده
The power conversion efficiency of CdSe and CdS quantum dot sensitized solar cells is enhanced by passivation with asymmetrically substituted phthalocyanines. The introduction of the phthalocyanine dye increases the efficiency up to 45% for CdSe and 104% for CdS. The main mechanism causing this improvement is the quantum dot passivation. This study highlights the possibilities of a new generation of dyes designed to be directly linked to QDs instead of the TiO2 electrodes.
منابع مشابه
SILAR Sensitization as an Effective Method for Making Efficient Quantum Dot Sensitized Solar Cells
CdSe quantum dots were in situ deposited on various structures of TiO2 photoanode by successive ionic layer adsorption and reaction (SILAR). Various sensitized TiO2 structures were integrated as a photoanode in order to make quantum dot sensitized solar cells. High power conversion efficiency was obtained; 2.89 % (Voc=524 mV, Jsc=9.78 mA/cm2, FF=0.56) for the cells that sensitized by SILAR meth...
متن کاملEffect of PbS Film Thickness on the Performance of Colloidal Quantum Dot Solar Cells
Colloidal quantum dots offer broad tuning of semiconductor band structure via the quantum size effect. In this paper, we present a detailed investigation on the influence of the thickness of colloidal lead sulfide (PbS) nanocrystals (active layer) to the photovoltaic performance of colloidal quantum dot solar cells. The PbS nanocrystals (QDs) were synthesized in a non-coordinating solvent, 1-oc...
متن کاملIntroducing nanostructure patterns for performance enhancement in PbS colloidal quantum dot solar cells
With attention to the thin film structure of colloidal quantum dot solar cells, in this paper in order to improvement of active layer absorption of them, we have proposed the use of nanostructure pattern for enhancement of their performance. For this purpose we have presented suitable nano hemisphare patterns in colloidal quantum dot solar cells for light trapping in absorption layer. Then with...
متن کاملRestricted charge recombination process in PbS quantum dot sensitized solar cells by different coating cycles of ZnS films
The relatively low power conversion efficiency (PCE) of quantum dot sensitized solar cells (QDSSCs) is attributed to charge recombination at the interfaces. Charge recombination process could be suppressed by coating the QD layer with a wide band gap semiconductor such as ZnS, which acts as a blocking layer between the QDs and hole transport material (HTM). In present study, to improve PCE of P...
متن کاملOptimization of Thermalisation Loss in the Quantum Dot Solar Cells using a Finite Element Method
As thermalisation loss is the dominant loss process in the quantum dot intermediate band solar cells (QD-IBSCs), it has been investigated and calculated for a QD-IBSC, where IB is created by embedding a stack of InAs(1-x) Nx QDs with a square pyramid shape in the intrinsic layer of the AlPySb(1-y) p-i-n structure. IB, which is an optically coupled but electrically isolated mini-band, divides th...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 51 9 شماره
صفحات -
تاریخ انتشار 2015